FactSage FTsalt salt database
List of systems and phases
The following tables summarize the contents of the FactSage FTsalt molten salt database in terms of the systems and phases it includes. The listings assist in phase selection for particular calculations by providing:
- A LIST OF all binary, QUASIBINARY, PSEUDOBINARY, ternary and RECIPROCAL TERNARY SYSTEMS WHICH HAVE BEEN ASSESSED
- A LIST OF ALL ASSESSED phases IN EACH OF THE SYSTEMS
- ASSiSTANCE WITH PHASE SELECTION
Phase diagrams have been calculated for all the binary systems and for some quasibinary and pseudobinary sections using the assessed parameters contained in the database. The diagram for a particular binary, quasibinary or pseudobinary system can be viewed by clicking on the system as listed in Tables 1 and 2 below. The diagrams contain the names of the stable phases in each system. Tables 3 and 4 refer to the ternary systems and reciprocal ternary systems (those containing two cations and two anions) respectively, and provide guidance in phase selection for calculations in higher-order systems.
The phases listed for the binary and higher-order systems may be solution phases or stoichiometric compound phases (ST).
When searching for a particular system in the present four tables, use alphabetical order of:
- the cations for a common anion system (Tables 1 and 3)
- the anions for a common cation system (Table 1)
- the compounds (end-members) for a quasibinary or pseudobinary system (Table 2)
- the cations for a reciprocal ternary system …, ... // Cl, F (Table 4)
TABLE 1 : List of phases for BINARY systems :
Complete assessments based on all experimental data from the literature are available for most systems listed below. For a few systems, owing to the lack of relevant data, some estimations have been made based on chemically similar systems or available data for higher-order systems (these systems are clearly identified below).
Click on the system name to view the stable phase diagram calculated with the stored parameters.
Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.
(I-option) – the phase displays a miscibility gap; selection with the I-option is required.
AlCl3-based systems : AlCl3 is a highly volatile species. For all AlCl3-based systems, all gaseous species from the FACT53 compound database have been considered for the calculations, and calculations have been made at 1 bar total pressure. (The notation “(GAS)” is used). In several of these systems the calculated figures contain phase boundaries shown as dotted lines. These are condensed phase boundaries calculated for high pressures when the gas phase does not appear.
NiCl2-based systems : NiCl2 is a volatile species and, for all NiCl2-based systems, the calculated 1 bar total pressure isobar (obtained using all gaseous species from the FACT53 compound database) is superimposed to the calculated phase diagram.
The calculated phase diagrams are presented in 2 different sections:
- Common ANION systems (Anion = Br, CO3, Cl, F, I, NO3, OH or SO4)
- Common CATION systems (Cation = Ca, Cs, K, Li, Mg, Na or Rb)
Common ANION systems :
Anion = Br
ESalt-liquid CsBr-[KBr-RbBr](ss) AlkBr(ss)
ESalt-liquid CsBr(ST) LiCsBr2(ST) LiBr(ST)
ESalt-liquid CsBr(ST) NaBr(ST)
ESalt-liquid CsBr-[KBr-RbBr](ss) AlkBr(ss)
ESalt-liquid KBr(ST) LiBr(ST)
ESalt-liquid AlkBr(ss) (I-option)
ESalt-liquid AlkBr(ss)
ESalt-liquid AlkBr(ss) (I-option)
ESalt-liquid LiBr(ST) LiRbBr2(ST) RbBr(ST)
ESalt-liquid NaBr(ST) RbBr(ST)
Anion = CO3
FSalt-liquid K2CO3(ST2) K2CO3(ST) KLi(CO3)(ST)
Li2CO3(ST3) Li2CO3(ST2) Li2CO3(ST)
FSalt-liquid [Li],Na,K//SO4,CO3(ss) K,Na//CO3,SO4(ss)
Na2CO3-[K2CO3](LT) Na2CO3-[K2CO3](HT)
FSalt-liquid [Li],Na,K//SO4,CO3(ss) Li2CO3(ST3) Li2CO3(ST2)
Li2CO3(ST) Na2CO3(ST2) Na2CO3(ST)
Anion = Cl
CSalt-liquid (I-option) AlCl3(ST) CaAlCl5(ST) CaCl2(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) CoAl2Cl8(ST) CoCl2(ST)
(GAS)
(Note : estimated from experimental data for the NaCl-AlCl3-CoCl2 ternary system)
CSalt-liquid (I-option) AlCl3(ST) FeAl2Cl8(ST) FeCl2(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) KAlCl4(ST) KCl(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) LiAlCl4(ST) LiCl(ST)
(GAS)
CSalt-liquid(I-option) AlCl3(ST) MgAl2Cl8(ST) MgCl2(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) MnAl2Cl8(ST) MnCl2(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) NaAlCl4(ST) NaCl(ST)
(GAS)
CSalt-liquid (I-option) AlCl3(ST) NiAl2Cl8(ST) NiCl2(ST)
(GAS)
(Note : estimated from chemically similar systems like AlCl3-MgCl2)
DSalt-liquid BaCl2(ST2) BaCl2(ST) CaBaCl4(ST) CaCl2(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) CsBaCl3(ST) Cs2BaCl4(ST) CsCl(ST2) CsCl(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) K2BaCl4(ST) KCl(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) LiCl(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) MgBa2Cl6(ST) MgCl2(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) NaCl(ST)
DSalt-liquid BaCl2(ST2) BaCl2(ST) Rb2BaCl4(ST) RbCl(ST)
DSalt-liquid (Sr,Ba,[Ca])Cl2(HT) (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss)
BSalt-liquid CaCl2(ST) CoCl2(ST)
DSalt-liquid CaCl2(ST) CsCaCl3(ST) CsCl(ST2) CsCl(ST)
BSalt-liquid CaCl2(ST) FeCl2(ST)
BSalt-liquid CaCl2(ST) CaFeCl5(ST) FeCl3(ST)
(Note : estimated from experimental data for the CaCl2-MgCl2-MnCl2-FeCl3 quaternary system)
ASalt-liquid CaCl2(ST) KCl(ST) KCaCl3(ST)
ASalt-liquid CaCl2(ST) LiCl(ST)
ASalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) MgCl2(ST)
BSalt-liquid CaCl2(ST) MnCl2(ST)
ASalt-liquid AlkCl-ss_rocksalt CaCl2(ST)
BSalt-liquid CaCl2(ST) NiCl2(ST)
HSalt-liquid CaCl2(ST) PbCl2(ST)
DSalt-liquid CaCl2(ST) RbCaCl3(ST) RbCl(ST)
DSalt-liquid (Sr,Ba,[Ca])Cl2(HT) (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option)
GSalt-liquid CeCl3(ST) CsCe2Cl7(ST) Cs3CeCl6(ST) CsCl(ST2) CsCl(ST)
GSalt-liquid CeCl3(ST) K3Ce5Cl18(ST) K2CeCl5(ST) K3CeCl6(ST) KCl(ST)
GSalt-liquid CeCl3(ST) LiCl(ST)
GSalt-liquid CeCl3(ST) Na3Ce5Cl18(ST) NaCl(ST)
GSalt-liquid CeCl3(ST) RbCe2Cl7(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCl(ST)
BSalt-liquid MCl2_SOLID
BSalt-liquid CoCl2(ST) CoFe2Cl8(ST) FeCl3(ST)
(Note : estimated from experimental data for the MnCl2-FeCl3 system)
BSalt-liquid CoCl2(ST) KCoCl3(ST) K2CoCl4(ST)
KCl(ST)
BSalt-liquid BAlkCl-ss_rocksalt CoCl2(ST) LiCoCl3(ST) Li2CoCl4(ST) Li4CoCl6(ST)
BSalt-liquid MCl2_SOLID
BSalt-liquid MCl2_SOLID (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only and is not
based on experimental data.)
BSalt-liquid CoCl2(ST) Na2CoCl4(ST) NaCl(ST)
BSalt-liquid MCl2_SOLID (I-option)
DSalt-liquid AAlkCl-ss_rocksalt (I-option)
(Note : calculated phase boundaries below 470 oC are predicted only, and are not based
on experimental data.)
GSalt-liquid CsCl(ST2) CsCl(ST) Cs3LaCl6(ST) CsLa2Cl7(ST) LaCl3(ST)
DSalt-liquid CsCl(ST2) CsCl(ST) LiCs2Cl3(ST) LiCl(ST)
DSalt-liquid CsCl(ST2) CsCl(ST) Cs3MgCl5(ST)
Cs2MgCl4(ST) CsMgCl3(ST) CsMg3Cl7(ST) MgCl2(ST)
DSalt-liquid CsCl(ST2) CsCl(ST) NaCl(ST)
DSalt-liquid AAlkCl-ss_rocksalt CsCl(ST)
DSalt-liquid CsCl(ST2) CsCl(ST) CsSrCl3(ST) SrCl2(ST2) SrCl2(ST)
BSalt-liquid FeCl2(ST) FeCl3(ST) (GAS)
BSalt-liquid FeCl2(ST)
K2FeCl4(ST) KFeCl3(ST)
KCl(ST)
BSalt-liquid BAlkCl-ss_rocksalt FeCl2(ST) Li2FeCl4(ST)
Li6FeCl8(ST)
BSalt-liquid MCl2_SOLID
BSalt-liquid MCl2_SOLID
BSalt-liquid FeCl2(ST) Na2FeCl4(ST) NaCl(ST)
BSalt-liquid MCl2_SOLID (I-option)
BSalt-liquid FeCl3(ST) LiFeCl4(ST) LiCl(ST)
BSalt-liquid FeCl3(ST) MgFe2Cl8(ST) MgCl2(ST)
(Note : estimated from experimental data for the FeCl3-MnCl2 system)
BSalt-liquid FeCl3(ST) MnFe2Cl8(ST) MnCl2(ST)
BSalt-liquid FeCl3(ST) NiFe2Cl8(ST) NiCl2(ST)
(GAS)
(Note : estimated from experimental data for the FeCl3-MnCl2 system)
GSalt-liquid LaCl3(ST) K3La5Cl18(ST) K2LaCl5(ST)
KCl(ST)
ASalt-liquid KCl(ST) LiCl(ST)
ASalt-liquid KCl(ST) K3Mg2Cl7(ST) K2MgCl4(ST)
KMgCl3(ST) MgCl2(ST)
BSalt-liquid KCl(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
KMnCl3(ST) MnCl2(ST)
ASalt-liquid AAlkCl-ss_rocksalt (I-option)
BSalt-liquid KCl(ST) KNiCl3(ST) NiCl2(ST)
HSalt-liquid KCl(ST) K2PbCl4(ST) KPb2Cl5(ST) PbCl2(ST)
DSalt-liquid AlkCl-ss_rocksalt
DSalt-liquid KCl(ST) K2SrCl4(ST) KSr2Cl5(ST) SrCl2(ST2) SrCl2(ST)
GSalt-liquid LaCl3(ST) LiCl(ST)
GSalt-liquid LaCl3(ST) Na3La5Cl18(ST) NaCl(ST)
GSalt-liquid LaCl3(ST) RbLa2Cl7(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbCl(ST)
ASalt-liquid AAlkCl-ss_rocksalt MCl2_SOLID
BSalt-liquid BAlkCl-ss_rocksalt Li2MnCl4(ST) MnCl2(ST)
ASalt-liquid AAlkCl-ss_rocksalt (I-option)
BSalt-liquid BAlkCl-ss_rocksalt Li6NiCl8(ST) Li2NiCl4(ST) NiCl2(ST)
DSalt-liquid LiCl(ST) LiRbCl2(ST) RbCl(ST)
DSalt-liquid LiCl(ST) SrCl2(ST2) SrCl2(ST)
BSalt-liquid MCl2_SOLID
ASalt-liquid MgCl2(ST) NaMgCl3(ST) Na2MgCl4(ST)
NaCl(ST)
BSalt-liquid MCl2_SOLID (I-option)
(Note : estimated from experimental data for the NaCl-KCl-MgCl2-NiCl2 quaternary system)
DSalt-liquid MgCl2(ST) RbMgCl3(ST) Rb2MgCl4(ST) RbCl(ST)
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) MgCl2(ST) SrCl2(ST2)
BSalt-liquid MnCl2(ST) NaMn4Cl9(ST) Na2Mn3Cl8(ST) Na9Mn11Cl31(ST) Na2MnCl4(ST) Na6MnCl8(ST) NaCl(ST)
BSalt-liquid MCl2_SOLID (I-option)
BSalt-liquid NaCl(ST) NiCl2(ST)
HSalt-liquid NaCl(ST) PbCl2(ST)
DSalt-liquid AlkCl-ss_rocksalt (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
DSalt-liquid NaCl(ST) SrCl2(ST2) SrCl2(ST)
DSalt-liquid RbCl(ST) RbSrCl3(ST) RbSr2Cl5(ST) SrCl2(ST2) SrCl2(ST)
Anion = F
ASalt-liquid CaF2(ST2) CaF2(ST) KCaF3(ST)
KF(ST)
ASalt-liquid CaF2(ST2) CaF2(ST) LiF(ST)
ASalt-liquid CaF2(ST2) CaF2(ST) MgF2(ST)
ASalt-liquid CaF2(ST2) CaF2(ST) NaF(ST)
ESalt-liquid AlkF(ssA) KF(ST)
ESalt-liquid CsF(ST) LiCsF2(ST) LiF(ST)
ESalt-liquid CsF(ST) NaF(ST)
ESalt-liquid AlkF(ssA)
ASalt-liquid KF(ST) LiF(ST)
ASalt-liquid KF(ST) K2MgF4(ST) KMgF3(ST)
MgF2(ST)
ASalt-liquid AlkF(ssA) NaF(ST)
ESalt-liquid AlkF(ssA)
ASalt-liquid LiF-[MgF2](ss) MgF2-[LiF](ss)
ASalt-liquid LiF(ST) NaF-[LiF](ss)
ESalt-liquid LiF(ST) LiRbF2(ST) RbF(ST)
ASalt-liquid MgF2(ST) NaMgF3(ST) NaF(ST)
ESalt-liquid NaF(ST) RbF(ST)
Anion = I
ESalt-liquid CsI-[KI-RbI](ss) AlkI(ss)
ESalt-liquid CsI(ST) LiI(ST)
ESalt-liquid CsI(ST) NaI(ST)
ESalt-liquid CsI-[KI-RbI](ss) AlkI(ss)
ESalt-liquid KI(ST) LiI(ST)
ESalt-liquid AlkI(ss) (I-option)
ESalt-liquid AlkI(ss)
ESalt-liquid AlkI(ss)
ESalt-liquid LiI(ST) LiRbI2(ST) RbI(ST)
ESalt-liquid AlkI(ss) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
Anion = NO3
ESalt-liquid Rb,Cs,[K]//NO3(ss) Na,K,[Rb,Cs]//NO3(ss) CsNO3-[KNO3](ss) KNO3(ST)
ESalt-liquid CsNO3(ST2) CsNO3(ST) CsLi(NO3)2(ST) LiNO3(ST)
ESalt-liquid CsNO3(ST2) CsNO3(ST) NaNO3(ST2)
NaNO3(ST)
ESalt-liquid Rb,Cs,[K]//NO3(ss) CsNO3(ST) RbNO3(ST3)
RbNO3(ST2) RbNO3(ST)
(Note : calculated phase boundaries below 290 oC are predicted only, and are not based
on experimental data.)
ESalt-liquid KNO3(ST2) KNO3(ST) LiNO3(ST)
ESalt-liquid Na,K,[Rb,Cs]//NO3(ss) KNO3-[NaNO3](lt) NaNO3(ST)
ESalt-liquid Na,K,[Rb,Cs]//NO3(ss) Rb,Cs,[K]//NO3(ss) RbNO3(ST3)
RbNO3(ST2) RbNO3(ST) KNO3(ST)
(Note : calculated phase boundaries below 285 oC are predicted only, and are not based
on experimental data.)
ESalt-liquid LiNO3(ST) NaNO3(ST2) NaNO3(ST)
ESalt-liquid LiNO3(ST) RbNO3(ST4) RbNO3(ST3)
RbNO3(ST2) RbNO3(ST) LiRb(NO3)2(ST)
ESalt-liquid NaNO3(ST2) NaNO3(ST) NaRb3(NO3)4(ST) RbNO3(ST4) RbNO3(ST3) RbNO3(ST2) RbNO3(ST)
Anion = OH
DSalt-liquid CsOH(ST2) CsOH(ST) KOH(ST2) KOH(ST)
DSalt-liquid CsOH(ST) CsOH(ST2) CsLi5(OH)6(ST)
LiOH(ST)
DSalt-liquid CsOH(ST2) CsOH(ST) NaOH(ST2) NaOH(ST)
DSalt-liquid K,Rb,Cs,[Na]//OH(HT) CsOH(ST) RbOH(ST)
ASalt-liquid KOH(ST2) KOH(ST) Li2K(OH)3(ST)
LiOH(ST)
ASalt-liquid K,Rb,Cs,[Na]//OH(HT) KOH-RbOH-[NaOH](LT) NaOH(ST2)
NaOH(ST)
DSalt-liquid K,Rb,Cs,[Na]//OH(HT) KOH-RbOH-[NaOH](LT)
ASalt-liquid NaOH-[LiOH](ss) LiOH(ST) LiNa(OH)2(ST)
NaOH(ST)
DSalt-liquid LiOH(ST) Li2Rb(OH)3(ST) RbOH(ST2)
RbOH(ST)
DSalt-liquid NaOH(ST) NaOH(ST2) RbOH(ST) RbOH(ST2)
Anion = SO4
FSalt-liquid [Li],Na,K//SO4,CO3(ss) Li,Na,K//SO4,CO3(ss) K2SO4(ST) KLi(SO4)(ST3) KLi(SO4)(ST2) KLi(SO4)(ST) Li2SO4(ST)
FSalt-liquid [Li],Na,K//SO4,CO3(ss) K,Na//SO4,CO3(ss) K3Na(SO4)2
Na2SO4-[K2SO4](ss)
FSalt-liquid LiNaSO4 [Li],Na,K//SO4,CO3(ss) Li,Na,K//SO4,CO3(ss) Li2SO4(ST) Na2SO4(ST) LiNaSO4(ST)
Common CATION systems :
Cation = Ca
ASalt-liquid CaCl2(ST) CaFCl(ST) CaF2(ST2) CaF2(ST)
ASalt-liquid CaCl2(ST) CaO(ST) Ca5OCl8(ST2)
Ca5OCl8(ST)
Cation = Cs
ESalt-liquid Cs-Halides(ss) CsCl-[CsBr-CsI](ss) CsCl(ST)
(Note : calculated phase boundaries below 610 oC are predicted only, and are not based
on experimental data.)
ESalt-liquid CsBr(ST) CsF(ST)
ESalt-liquid Cs-Halides(ss) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
ESalt-liquid CsNO3-CsBr(ss) (I-option) CsNO3(ST)
(Note : the calculated subsolidus is predicted only and is not based on experimental data.)
ESalt-liquid CsCl(ST2) CsCl(ST) CsF(ST)
ESalt-liquid CsCl-[CsBr-CsI](ss) Cs-Halides(ss) CsCl(ST)
ESalt-liquid CsCl-[CsNO3](ss) CsNO3-[CsCl](ss) CsCl(ST)
CsNO3(ST)
ESalt-liquid CsF(ST) CsI(ST)
ESalt-liquid CsF(ST) CsNO3(ST2) CsNO3(ST)
ESalt-liquid CsNO3-[CsOH](HT) CsNO3-[CsOH](LT) CsOH-[CsNO3](ss) CsOH(ST)
Cation = K
ESalt-liquid K-Halides(ssA)
ESalt-liquid KBr(ST) KF(ST)
ESalt-liquid K-Halides(ssA) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
ESalt-liquid KNO3-[KBr](ss) KBr(ST) KNO3(ST)
ESalt-liquid KOH-[KBr](ss) KBr(ST) KOH(ST)
FSalt-liquid KCl(ST) K2CO3(ST2) K2CO3(ST)
FSalt-liquid K2CO3(ST2) K2CO3(ST) K3F(CO3)(ST) KF(ST)
FSalt-liquid K2CO3(ST2) K2CO3(ST) KNO3(ST2)
KNO3(ST)
FSalt-liquid K2CO3(ST2) K2CO3(ST) KOH(ST2)
KOH(ST)
FSalt-liquid [Li],Na,K//SO4,CO3(ss) K,Na//CO3,SO4(ss)
K,Na//SO4,CO3(ss) (I-option)
ASalt-liquid KCl(ST) KF(ST)
ESalt-liquid K-Halides(ssA) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only, and is not
based on experimental data.)
ESalt-liquid KCl(ST) K2ClNO3(ST) KNO3(ST2)
KNO3(ST)
ASalt-liquid KCl-KOH(ss) (I-option) KOH(ST)
FSalt-liquid KCl(ST) K2SO4(ST2) K2SO4(ST)
ESalt-liquid KF(ST) KI(ST)
ESalt-liquid KF(ST) KNO3(ST2) KNO3(ST)
ASalt-liquid KF-KOH(ss) (I-option) KOH(ST)
FSalt-liquid KF(ST) K3F(SO4)(ST) K2SO4(ST2)
K2SO4(ST)
ESalt-liquid KI(ST) KNO3-[KI](ss) KNO3(ST)
ESalt-liquid KI(ST) KOH(ST2) KOH(ST)
ESalt-liquid KNO3(ST2) KNO3(ST) K2(OH)(NO3)(ST)
KOH(ST2) KOH(ST)
FSalt-liquid KNO3(ST2) KNO3(ST) K2SO4(ST2)
K2SO4(ST)
FSalt-liquid KOH(ST2) KOH(ST) K2SO4(ST2)
K2SO4(ST)
Cation = Li
ESalt-liquid Li-Halides(ss)(I-option)
(Note : The calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
ESalt-liquid LiBr(ST) LiNO3(ST)
ESalt-liquid LiBr(ST) Li2OHBr(ST) Li4(OH)3Br(ST)
LiOH(ST)
ESalt-liquid LiBr(ST) LiF(ST)
ESalt-liquid Li-Halides(ss) )(I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
FSalt-liquid LiCl(ST) Li2CO3(ST3) Li2CO3(ST2)
Li2CO3(ST)
FSalt-liquid Li2CO3(ST3) Li2CO3(ST2) Li2CO3(ST)
LiF(ST)
FSalt-liquid Li2CO3(ST3) Li2CO3(ST2) Li2CO3(ST)
LiNO3(ST)
FSalt-liquid Li2CO3(ST3) Li2CO3(ST2) Li2CO3(ST)
LiOH(ST)
FSalt-liquid Li,Na,K//SO4,CO3(ss) Li2CO3(ST3) Li2CO3(ST2) Li2CO3(ST) Li2SO4(ST)
ASalt-liquid LiCl(ST) LiF(ST)
ESalt-liquid LiCl(ST) LiI(ST)
ESalt-liquid LiCl(ST) LiNO3(ST)
ASalt-liquid LiCl(ST) LiOH(ST) Li2OHCl(ST)
FSalt-liquid LiCl(ST) Li2SO4(ST2) Li2SO4(ST)
ESalt-liquid LiF(ST) LiI(ST)
ESalt-liquid LiF(ST) LiNO3(ST)
ASalt-liquid LiF(ST) LiOH(ST)
FSalt-liquid LiF(ST) Li2SO4(ST2) Li2SO4(ST)
ESalt-liquid LiI(ST) Li2OHI(ST) Li5(OH)4I(ST)
LiOH(ST)
ESalt-liquid LiNO3(ST) Li2OHNO3(ST) LiOH(ST)
FSalt-liquid LiNO3(ST) Li2SO4(ST2) Li2SO4(ST)
FSalt-liquid LiOH(ST) Li2SO4(ST2) Li2SO4(ST)
Cation = Mg
ASalt-liquid MgCl2(ST) MgF2(ST)
ASalt-liquid MgCl2(ST) MgO(ST)
ASalt-liquid MgF2(ST) MgO(ST)
Cation = Na
ESalt-liquid Na-Halides(ssA)
ESalt-liquid NaBr(ST) NaF(ST)
ESalt-liquid Na-Halides(ssA)
ESalt-liquid NaBr(ST) NaNO3(ST2) NaNO3(ST)
ESalt-liquid NaBr(ST) NaOH(ST2) NaOH(ST)
FSalt-liquid NaCl(ST) Na2CO3(ST3) Na2CO3(ST2)
Na2CO3(ST)
FSalt-liquid Na2CO3(ST3) Na2CO3(ST2) Na2CO3(ST)
NaF(ST)
FSalt-liquid Na2CO3(ST3)
Na2CO3(ST2) Na2CO3(ST)
NaNO3(ST2) NaNO3(ST)
FSalt-liquid Na2CO3(ST3) Na2CO3(ST2) Na2CO3(ST)
NaOH(ST2) NaOH(ST)
FSalt-liquid [Li],Na,K//SO4,CO3(ss) Na2CO3(ST2) Na2CO3(ST) Na2SO4(ST)
ASalt-liquid NaCl(ST) NaF(ST)
ESalt-liquid Na-Halides(ssA) Na-Halides(ssB)
ESalt-liquid NaCl(ST) NaNO3(ST2) NaNO3(ST)
ASalt-liquid NaCl-[NaOH](ss) NaOH-[NaCl](ss) NaOH(ST)
FSalt-liquid NaCl(ST) Na2SO4(ST2) Na2SO4(ST)
ESalt-liquid NaF(ST) NaI(ST)
ESalt-liquid NaF(ST) NaNO3(ST2) NaNO3(ST)
ASalt-liquid NaF-NaOH(ss) (I-option) NaOH(ST)
FSalt-liquid NaF(ST) Na3F(SO4)(ST) Na2SO4(ST2)
Na2SO4(ST)
ESalt-liquid NaI(ST) NaNO3-[NaI](ss) NaNO3(ST)
ESalt-liquid NaI(ST) Na5OHI4(ST) NaOH(ST2) NaOH(ST)
ESalt-liquid NaNO3(ST2) NaNO3(ST) Na2OHNO3(ST) Na3(OH)2(NO3)(ST) NaOH(ST2) NaOH(ST)
FSalt-liquid NaNO3(ST2) NaNO3(ST) Na2SO4(ST2)
Na2SO4(ST)
FSalt-liquid NaOH(ST2) NaOH(ST) Na3(OH)(SO4)(ST)
Na2SO4(ST2) Na2SO4(ST)
Cation = Rb
ESalt-liquid Rb-Halides(ss)
ESalt-liquid RbBr(ST) RbF(ST)
ESalt-liquid Rb-Halides(ss) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
ESalt-liquid RbNO3-RbBr(ss) RbNO3(ST3) RbNO3(ST2)
RbNO3(ST)
(Note : calculated phase boundaries below 300 oC are predicted only, and are not based
on experimental data.)
ESalt-liquid RbCl(ST) RbF(ST)
ESalt-liquid Rb-Halides(ss) (I-option)
(Note : the calculated solid-solid miscibility gap at low temperature is predicted only,
and is not based on experimental data.)
DSalt-liquid RbCl-[RbOH](ss) RbOH-[RbCl](ss) RbOH(ST)
ESalt-liquid RbF(ST) RbI(ST)
ESalt-liquid RbNO3(ST4) RbNO3(ST3) RbNO3(ST2)
RbNO3(ST) Rb2OHNO3(ST) RbOH(ST2) RbOH(ST)
TABLE 2 : List of phases for QUASIBINARY
and/or PSEUDOBINARY sections :
Complete assessments based on all experimental data from the literature are available for the sections listed below. That is, these are the sections for which experimental data are available and have been used in the optimizations.
Click on the system name to view the stable phase diagram calculated with the stored parameters.
Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.
(I-option) – the phase displays a miscibility gap; selection with the I-option is required.
AlCl3-based systems : AlCl3 is a highly volatile species. For all AlCl3-based systems, all gaseous species from the FACT53 compound database have been considered for the calculations, and calculations have been made at 1 bar total pressure. (The notation “(GAS)” is used). In some of these systems the calculated figures contain phase boundaries shown as dotted lines. These are condensed phase boundaries calculated for high pressures when the gas phase does not appear.
ASalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) MgF2(ST) CaFCl(ST)
CSalt-liquid (I-option) CaCl2(ST) NaAlCl4(ST) (GAS)
ASalt-liquid CAMX3-Perovskite CaF2(ST2) CaF2(ST)
KCl(ST) CaFCl(ST)
(Note : The system has been optimized only in the composition range XKCaCl3 > 0.4)
CSalt-liquid (I-option) KAlCl4(ST) NaAlCl4(ST)
CSalt-liquid(I-option) AAlkCl-ss_rocksalt KAlCl4(ST) NaAlCl4(ST)
ASalt-liquid KCl(ST) LiF(ST) KF(ST)
LiCl(ST)
CSalt-liquid(I-option) AAlkCl-ss_rocksalt(I-option) KAlCl4(ST)
NaAlCl4(ST)
BSalt-liquid BAlkCl-ss_rocksalt FeCl2(ST) KFeCl3(ST)
ASalt-liquid AAMX3-Perovskite AAlk2MX4 AAlkCl-ss_rocksalt K3Mg2Cl7(ST) LiKMgCl4(ST)
ASalt-liquid AAMX3-Perovskite AAlk2MX4 AAlkCl-ss_rocksalt
K3Mg2Cl7(ST)
BSalt-liquid BAlkCl-ss_rocksalt KMnCl3(ST) Na6MnCl8(ST)
CSalt-liquid (I-option) LiAlCl4(ST) NaAlCl4(ST)
ASalt-liquid AAlkCl-ss_rocksalt LiF(ST) NaF-[LiF](ss)
TABLE 3 : List of phases for common-ion TERNARY systems with Cl or F:
Only the MAIN ternary systems are presented below. These are the common ANION systems with anion = Cl or F.
Ternary phase diagrams may be calculated using the phases listed below for each system. The following code of colours is used:
- For all ternary systems in purple, complete assessments based on all experimental data from the literature are available. Ternary parameters were added for the liquid and/or other phases (solid solutions) if needed.
- For all ternary systems in blue, no experimental data could be found in the literature. Consequently, the thermodynamic properties of the liquid (and solid solutions if they exist) are simply estimated from the optimized parameters of the binary subsystems using proper interpolation methods.
Beware - if some ternary phases are unknown, incorrect phase equilibria may be calculated.
Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.
(I-option) ― the phase displays a 2-phase immiscibility; selection with the I-option is required.
(J-option) ― the phase may display a 3-phase immiscibility; selection with the J-option is required.
Note: AlCl3 and NiCl2 are volatile. Under certain conditions, the total gas pressure may be greater than 1 bar. In this case, the gas phase should also be selected using all gases from the FACT53 compound database.
Anion = Cl
AlCl3-CaCl2-CoCl2
CSalt-liquid (J-option) AlCl3(ST) CaCl2(ST) CaAlCl5(ST) CoCl2(ST) CoAl2Cl8(ST)
AlCl3-CaCl2-FeCl2
CSalt-liquid (J-option) AlCl3(ST) CaCl2(ST) CaAlCl5(ST)
FeCl2(ST) FeAl2Cl8(ST)
AlCl3-CaCl2-FeCl3
CSalt-liquid (J-option) AlCl3(ST) CaCl2(ST) CaAlCl5(ST) FeCl3(ST) CaFeCl5(ST)
AlCl3-CaCl2-KCl
CSalt-liquid (J-option) KCl(ST) AlCl3(ST) KAlCl4(ST) CaCl2(ST) CaAlCl5(ST) KCaCl3(ST)
AlCl3-CaCl2-LiCl
CSalt-liquid (J-option) LiCl(ST) AlCl3(ST) LiAlCl4(ST) CaCl2(ST) CaAlCl5(ST)
AlCl3-CaCl2-MgCl2
CSalt-liquid (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) MgCl2(ST) AlCl3(ST) MgAl2Cl8(ST) CaAlCl5(ST)
AlCl3-CaCl2-MnCl2
CSalt-liquid (J-option) AlCl3(ST) CaCl2(ST) CaAlCl5(ST) MnCl2(ST) MnAl2Cl8(ST)
AlCl3-CaCl2-NaCl
CSalt-liquid (J-option) AAlkCl-ss_rocksalt (J-option) AlCl3(ST) NaAlCl4(ST) CaCl2(ST) CaAlCl5(ST)
AlCl3-CaCl2-NiCl2
CSalt-liquid (J-option) AlCl3(ST) CaCl2(ST) CaAlCl5(ST) NiCl2(ST) NiAl2Cl8(ST)
AlCl3-CoCl2-FeCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) FeAl2Cl8(ST) CoAl2Cl8(ST) CoFe2Cl8(ST)
AlCl3-CoCl2-FeCl3
CSalt-liquid (J-option) AlCl3(ST) FeCl3(ST) CoCl2(ST) CoAl2Cl8(ST) CoFe2Cl8(ST)
AlCl3-CoCl2-KCl
CSalt-liquid (J-option) KCl(ST) AlCl3(ST) KAlCl4(ST) CoCl2(ST) CoAl2Cl8(ST) KCoCl3(ST) K2CoCl4(ST)
AlCl3-CoCl2-LiCl
CSalt-liquid (J-option) BAlkCl-ss_rocksalt (J-option) AlCl3(ST) LiAlCl4(ST) CoCl2(ST) LiCoCl3(ST) Li2CoCl4(ST) Li4CoCl6(ST) CoAl2Cl8(ST)
AlCl3-CoCl2-MgCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) MgAl2Cl8(ST) CoAl2Cl8(ST)
AlCl3-CoCl2-MnCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) MnAl2Cl8(ST) CoAl2Cl8(ST)
AlCl3-CoCl2-NaCl
CSalt-liquid (J-option) NaCl(ST) AlCl3(ST) NaAlCl4(ST) CoCl2(ST) Na2CoCl4(ST) CoAl2Cl8(ST)
AlCl3-CoCl2-NiCl2
CSalt-liquid (J-option) MCl2_SOLID(I-option) AlCl3(ST) CoAl2Cl8(ST) NiAl2Cl8(ST)
AlCl3-FeCl2-FeCl3
CSalt-liquid (J-option) AlCl3(ST) FeCl2(ST) FeCl3(ST) FeAl2Cl8(ST)
AlCl3-FeCl2-KCl
CSalt-liquid (J-option) KCl(ST) AlCl3(ST) KAlCl4(ST) FeCl2(ST) FeAl2Cl8(ST) KFeCl3(ST) K2FeCl4(ST)
AlCl3-FeCl2-LiCl
CSalt-liquid (J-option) BAlkCl-ss_rocksalt (J-option) AlCl3(ST) LiAlCl4(ST) FeCl2(ST) Li2FeCl4(ST) Li6FeCl8(ST) FeAl2Cl8(ST)
AlCl3-FeCl2-MgCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) MgAl2Cl8(ST) FeAl2Cl8(ST)
AlCl3-FeCl2-MnCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) MnAl2Cl8(ST) FeAl2Cl8(ST)
AlCl3-FeCl2-NaCl
CSalt-liquid (J-option) NaCl(ST) AlCl3(ST) NaAlCl4(ST) FeCl2(ST) Na2FeCl4(ST) FeAl2Cl8(ST)
AlCl3-FeCl2-NiCl2
CSalt-liquid (J-option) MCl2_SOLID(I-option) AlCl3(ST) FeAl2Cl8(ST) NiAl2Cl8(ST)
AlCl3-FeCl3-KCl
CSalt-liquid (J-option) AlCl3(ST) KCl(ST) KAlCl4(ST) FeCl3(ST) KFeCl4(ST)
AlCl3-FeCl3-LiCl
CSalt-liquid (J-option) LiCl(ST) AlCl3(ST) LiAlCl4(ST) FeCl3(ST) LiFeCl4(ST)
AlCl3-FeCl3-MgCl2
CSalt-liquid (J-option) MgCl2(ST) AlCl3(ST) MgAl2Cl8(ST) FeCl3(ST) MgFe2Cl8(ST)
AlCl3-FeCl3-MnCl2
CSalt-liquid (J-option) AlCl3(ST) MnCl2(ST) MnAl2Cl8(ST) FeCl3(ST) MnFe2Cl8(ST)
AlCl3-FeCl3-NaCl
CSalt-liquid (J-option) NaCl(ST) AlCl3(ST) NaAlCl4(ST) FeCl3(ST) NaFeCl4(ST)
AlCl3-FeCl3-NiCl2
CSalt-liquid (J-option) AlCl3(ST) FeCl3(ST) NiCl2(ST) NiAl2Cl8(ST) NiFe2Cl8(ST)
AlCl3-KCl-LiCl
CSalt-liquid (J-option) KCl(ST) LiCl(ST) AlCl3(ST) LiAlCl4(ST) KAlCl4(ST)
AlCl3-KCl-MgCl2
CSalt-liquid (J-option) KCl(ST) MgCl2(ST) AlCl3(ST)
MgAl2Cl8(ST) KMgCl3(ST) K2MgCl4(ST) K3Mg2Cl7(ST) KAlCl4(ST)
AlCl3-KCl-MnCl2
CSalt-liquid (J-option) KCl(ST) AlCl3(ST) KAlCl4(ST) MnCl2(ST) MnAl2Cl8(ST) KMnCl3(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
AlCl3-KCl-NaCl
CSalt-liquid (J-option) AAlkCl-ss_rocksalt (J-option) AlCl3(ST) NaAlCl4(ST) KAlCl4(ST)
AlCl3-KCl-NiCl2
CSalt-liquid (J-option) KCl(ST) AlCl3(ST) KAlCl4(ST) NiCl2(ST) NiAl2Cl8(ST) KNiCl3(ST)
AlCl3-LiCl-MgCl2
CSalt-liquid (J-option) MCl2_SOLID AAlkCl-ss_rocksalt (J-option)
AlCl3(ST) LiAlCl4(ST) MgAl2Cl8(ST)
AlCl3-LiCl-MnCl2
CSalt-liquid (J-option) BAlkCl-ss_rocksalt (J-option) AlCl3(ST) LiAlCl4(ST) MnCl2(ST) Li2MnCl4(ST) MnAl2Cl8(ST)
AlCl3-LiCl-NaCl
CSalt-liquid (J-option) AAlkCl-ss_rocksalt (J-option) AlCl3(ST) LiAlCl4(ST) NaAlCl4(ST)
AlCl3-LiCl-NiCl2
CSalt-liquid (J-option) BAlkCl-ss_rocksalt (J-option) AlCl3(ST) LiAlCl4(ST) NiCl2(ST) Li2NiCl4(ST) Li6NiCl8(ST) NiAl2Cl8(ST)
AlCl3-MgCl2-MnCl2
CSalt-liquid (J-option) MCl2_SOLID AlCl3(ST) MgAl2Cl8(ST) MnAl2Cl8(ST)
AlCl3-MgCl2-NaCl
CSalt-liquid (J-option) NaCl(ST) MgCl2(ST) NaMgCl3(ST) Na2MgCl4(ST) AlCl3(ST) NaAlCl4(ST) MgAl2Cl8(ST)
AlCl3-MgCl2-NiCl2
CSalt-liquid (J-option) MCl2_SOLID (I-option) AlCl3(ST) MgAl2Cl8(ST) NiAl2Cl8(ST)
AlCl3-MnCl2-NaCl
CSalt-liquid (J-option) NaCl(ST) AlCl3(ST) NaAlCl4(ST) MnCl2(ST) Na2MnCl4(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST) MnAl2Cl8(ST)
AlCl3-MnCl2-NiCl2
CSalt-liquid (J-option) MCl2_SOLID (I-option) AlCl3(ST) MnAl2Cl8(ST) NiAl2Cl8(ST)
AlCl3-NaCl-NiCl2
CSalt-liquid (J-option) NaCl(ST) AlCl3(ST) NaAlCl4(ST) NiCl2(ST) NiAl2Cl8(ST)
BaCl2-CaCl2-CsCl
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) BAlk2MX4(J-option) BaCl2(ST) CsCl(ST)
CsCl(ST2) CaBaCl4(ST)
BaCl2-CaCl2-KCl
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) BAlk2MX4(J-option) KCl(ST) BaCl2(ST) CaBaCl4(ST)
BaCl2-CaCl2-LiCl
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) LiCl(ST)
BaCl2(ST) CaBaCl4(ST)
BaCl2-CaCl2-MgCl2
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) MgCl2(ST) BaCl2(ST) MgBa2Cl6(ST) CaBaCl4(ST)
BaCl2-CaCl2-NaCl
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT)
AAlkCl-ss_rocksalt (J-option) BaCl2(ST) CaBaCl4(ST)
BaCl2-CaCl2-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) BAlk2MX4(J-option) RbCl(ST) BaCl2(ST) CaBaCl4(ST)
BaCl2-CaCl2-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT) CaBaCl4(ST)
BaCl2-CsCl-KCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
AAlkCl-ss_rocksalt (J-option) CsCl(ST) BaCl2(ST) BaCl2(ST2)
BaCl2-CsCl-LiCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
LiCl(ST) CsCl(ST) CsCl(ST2) LiCs2Cl3(ST)
BaCl2(ST) BaCl2(ST2)
BaCl2-CsCl-MgCl2
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option) MgCl2(ST) CsCl(ST) CsCl(ST2) CsMg3Cl7(ST) Cs3MgCl5(ST) BaCl2(ST) BaCl2(ST2) MgBa2Cl6(ST)
BaCl2-CsCl-NaCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
CsCl(ST) CsCl(ST2) NaCl(ST) BaCl2(ST) BaCl2(ST2)
BaCl2-CsCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
AAlkCl-ss_rocksalt (J-option) CsCl(ST) BaCl2(ST)
BaCl2(ST2)
BaCl2-CsCl-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) BAlk2MX4 (J-option) CsCl(ST) CsCl(ST2)
BaCl2-KCl-LiCl
DSalt-liquid BAlk2MX4 (J-option) KCl(ST) LiCl(ST)
BaCl2(ST) BaCl2(ST2)
BaCl2-KCl-MgCl2
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option) KCl(ST) MgCl2(ST) K3Mg2Cl7(ST) BaCl2(ST) BaCl2(ST2) MgBa2Cl6(ST)
BaCl2-KCl-NaCl
DSalt-liquid BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option)
BaCl2(ST) BaCl2(ST2)
BaCl2-KCl-RbCl
DSalt-liquid BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option)
BaCl2(ST) BaCl2(ST2)
BaCl2-KCl-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) AlkM2Cl5(I-option) BAlk2MX4 (J-option) KCl(ST)
BaCl2-LiCl-MgCl2
DSalt-liquid MCl2_SOLID AAlkCl-ss_rocksalt (J-option)
BaCl2(ST) BaCl2(ST2) MgBa2Cl6(ST)
BaCl2-LiCl-NaCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) BaCl2(ST) BaCl2(ST2)
BaCl2-LiCl-RbCl
DSalt-liquid BAlk2MX4 (J-option) LiCl(ST) RbCl(ST)
LiRbCl2(ST) BaCl2(ST) BaCl2(ST2)
BaCl2-LiCl-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT)
LiCl(ST)
BaCl2-MgCl2-NaCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
NaCl(ST) MgCl2(ST) BaCl2(ST) BaCl2(ST2) MgBa2Cl6(ST) Na3Mg2BaCl9(ST)
BaCl2-MgCl2-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
RbCl(ST) MgCl2(ST) BaCl2(ST) BaCl2(ST2) MgBa2Cl6(ST)
BaCl2-MgCl2-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT)
MgCl2(ST) MgBa2Cl6(ST)
BaCl2-NaCl-RbCl
DSalt-liquid BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option)
BaCl2(ST) BaCl2(ST2)
BaCl2-NaCl-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) NaCl(ST)
BaCl2-RbCl-SrCl2
DSalt-liquid (Ba,[Sr])Cl2(LT) BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) (Sr,Ba,[Ca])Cl2(HT) AlkM2Cl5 (I-option) BAlk2MX4 (J-option)
RbCl(ST)
CaCl2-CoCl2-FeCl2
BSalt-liquid MCl2_SOLID CaCl2(ST)
CaCl2-CoCl2-FeCl3
BSalt-liquid CaCl2(ST) FeCl3(ST) CaFeCl5(ST) CoCl2(ST) CoFe2Cl8(ST)
CaCl2-CoCl2-KCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
KCl(ST) CaCl2(ST) CoCl2(ST)
CaCl2-CoCl2-LiCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) CaCl2(ST) CoCl2(ST)
Li4CoCl6(ST)
CaCl2-CoCl2-MgCl2
BSalt-liquid MCl2_SOLID (Ca,Sr,[Ba,Mg])Cl2(ss)
CaCl2-CoCl2-MnCl2
BSalt-liquid MCl2_SOLID CaCl2(ST)
CaCl2-CoCl2-NaCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) CaCl2(ST) CoCl2(ST)
CaCl2-CoCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) CaCl2(ST)
CaCl2-CsCl-KCl
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST) CsCl(ST)
CaCl2-CsCl-LiCl
DSalt-liquid BAMX3-Perovskite (J-option) CaCl2(ST) CsCl(ST) CsCl(ST2) LiCl(ST) LiCs2Cl3(ST)
CaCl2-CsCl-MgCl2
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss)
BAlk2MX4 (J-option) MgCl2(ST) CsCl(ST) CsCl(ST2)
CsMg3Cl7(ST) Cs3MgCl5(ST)
CaCl2-CsCl-NaCl
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST) CsCl(ST)
CaCl2-CsCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST) CsCl(ST)
CaCl2-CsCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option)
(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT)
CsCl(ST) CsCl(ST2)
CaCl2-FeCl2-FeCl3
BSalt-liquid CaCl2(ST) FeCl2(ST) FeCl3(ST) CaFeCl5(ST)
CaCl2-FeCl2-KCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
KCl(ST) CaCl2(ST) FeCl2(ST)
CaCl2-FeCl2-LiCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
CaCl2(ST) FeCl2(ST) Li6FeCl8(ST)
CaCl2-FeCl2-MgCl2
BSalt-liquid MCl2_SOLID (Ca,Sr,[Ba,Mg])Cl2(ss)
CaCl2-FeCl2-MnCl2
BSalt-liquid MCl2_SOLID CaCl2(ST)
CaCl2-FeCl2-NaCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) CaCl2(ST) FeCl2(ST)
CaCl2-FeCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) CaCl2(ST)
CaCl2-FeCl3-KCl
BSalt-liquid KCl(ST) CaCl2(ST) KCaCl3(ST) FeCl3(ST) KFeCl4(ST) CaFeCl5(ST)
CaCl2-FeCl3-LiCl
BSalt-liquid LiCl(ST) CaCl2(ST) FeCl3(ST) LiFeCl4(ST) CaFeCl5(ST)
CaCl2-FeCl3-MgCl2
BSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) MgCl2(ST) FeCl3(ST)
MgFe2Cl8(ST) CaFeCl5(ST)
CaCl2-FeCl3-MnCl2
BSalt-liquid CaCl2(ST) MnCl2(ST) FeCl3(ST) CaFeCl5(ST) MnFe2Cl8(ST)
CaCl2-FeCl3-NaCl
BSalt-liquid BAlkCl-ss_rocksalt (J-option) CaCl2(ST) FeCl3(ST) NaFeCl4(ST) CaFeCl5(ST)
CaCl2-FeCl3-NiCl2
BSalt-liquid CaCl2(ST) FeCl3(ST) CaFeCl5(ST) NiCl2(ST) NiFe2Cl8(ST)
CaCl2-KCl-LiCl
ASalt-liquid AAMX3-Perovskite (J-option) KCl(ST)
LiCl(ST) CaCl2(ST)
CaCl2-KCl-MgCl2
ASalt-liquid AAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss)
AAlk2MX4 (J-option) KCl(ST) MgCl2(ST) K3Mg2Cl7(ST)
CaCl2-KCl-MnCl2
BSalt-liquid AAMX3-Perovskite (J-option) KCl(ST)
CaCl2(ST) MnCl2(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
CaCl2-KCl-NaCl
ASalt-liquid AAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST)
CaCl2-KCl-NiCl2
BSalt-liquid AAMX3-Perovskite (J-option) KCl(ST)
CaCl2(ST) NiCl2(ST)
CaCl2-KCl-PbCl2
HSalt-liquid KCl(ST) CaCl2(ST) KCaCl3(ST) PbCl2(ST) K2PbCl4(ST) KPb2Cl5(ST)
CaCl2-KCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST)
CaCl2-KCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option)
(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT) BAlk2MX4 (J-option) KCl(ST) KSr2Cl5(ST)
CaCl2-LiCl-MgCl2
ASalt-liquid MCl2_SOLID (Ca,Sr,[Ba,Mg])Cl2(ss)
AAlkCl-ss_rocksalt (J-option)
CaCl2-LiCl-MnCl2
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
CaCl2(ST) MnCl2(ST)
CaCl2-LiCl-NaCl
ASalt-liquid AAlkCl-ss_rocksalt (J-option) CaCl2(ST)
CaCl2-LiCl-NiCl2
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
CaCl2(ST) NiCl2(ST) Li6NiCl8(ST)
CaCl2-LiCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) LiCl(ST)
RbCl(ST) CaCl2(ST) LiRbCl2(ST)
CaCl2-LiCl-SrCl2
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT)
LiCl(ST)
CaCl2-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID (Ca,Sr,[Ba,Mg])Cl2(ss)
CaCl2-MgCl2-NaCl
ASalt-liquid AAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) AAlk2MX4(J-option) AAlkCl-ss_rocksalt (J-option) MgCl2(ST)
CaCl2-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) (Ca,Sr,[Ba,Mg])Cl2(ss)
CaCl2-MgCl2-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) BAlk2MX4(J-option) RbCl(ST) MgCl2(ST)
CaCl2-MgCl2-SrCl2
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT) MgCl2(ST)
CaCl2-MnCl2-NaCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
CaCl2(ST) MnCl2(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
CaCl2-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) CaCl2(ST)
CaCl2-NaCl-NiCl2
BSalt-liquid BAlkCl-ss_rocksalt (J-option) CaCl2(ST) NiCl2(ST)
CaCl2-NaCl-PbCl2
HSalt-liquid AAlkCl-ss_rocksalt (J-option) CaCl2(ST) PbCl2(ST)
CaCl2-NaCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) CaCl2(ST)
CaCl2-NaCl-SrCl2
DSalt-liquid (Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT) AAlkCl-ss_rocksalt (J-option)
CaCl2-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option)
(Ca,Sr,[Ba,Mg])Cl2(ss) (I-option) (Sr,Ba,[Ca])Cl2(HT)
RbCl(ST) RbSr2Cl5(ST)
CeCl3-CsCl-KCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
CeCl3(ST) K2CeCl5(ST) K3CeCl6(ST) K3Ce5Cl18(ST) Cs3CeCl6(ST) CsCe2Cl7(ST)
CeCl3-CsCl-LaCl3
GSalt-liquid RareEarth-Chloride(ss) CsCl(ST) CsCl(ST2) Cs3LaCl6(ST) CsLa2Cl7(ST) Cs3CeCl6(ST) CsCe2Cl7(ST)
CeCl3-CsCl-LiCl
GSalt-liquid LiCl(ST) CsCl(ST) CsCl(ST2)
LiCs2Cl3(ST) CeCl3(ST) Cs3CeCl6(ST) CsCe2Cl7(ST)
CeCl3-CsCl-NaCl
GSalt-liquid NaCl(ST) CsCl(ST) CsCl(ST2)
CeCl3(ST) Na3Ce5Cl18(ST) Cs3CeCl6(ST) CsCe2Cl7(ST)
CeCl3-CsCl-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
CeCl3(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCe2Cl7(ST) Cs3CeCl6(ST) CsCe2Cl7(ST)
CeCl3-KCl-LaCl3
GSalt-liquid RareEarth-Chloride(ss) KCl(ST) K2LaCl5(ST) K3La5Cl18(ST) K2CeCl5(ST) K3CeCl6(ST) K3Ce5Cl18(ST)
CeCl3-KCl-LiCl
GSalt-liquid KCl(ST) LiCl(ST) CeCl3(ST) K2CeCl5(ST) K3CeCl6(ST) K3Ce5Cl18(ST)
CeCl3-KCl-NaCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CeCl3(ST) Na3Ce5Cl18(ST) K2CeCl5(ST) K3CeCl6(ST) K3Ce5Cl18(ST)
CeCl3-KCl-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CeCl3(ST) K2CeCl5(ST) K3CeCl6(ST) K3Ce5Cl18(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCe2Cl7(ST)
CeCl3-LaCl3-LiCl
GSalt-liquid RareEarth-Chloride(ss) LiCl(ST)
CeCl3-LaCl3-NaCl
GSalt-liquid RareEarth-Chloride(ss) NaCl(ST) Na3La5Cl18(ST) Na3Ce5Cl18(ST)
CeCl3-LaCl3-RbCl
GSalt-liquid RareEarth-Chloride(ss) RbCl(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbLa2Cl7(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCe2Cl7(ST)
CeCl3-LiCl-NaCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CeCl3(ST) Na3Ce5Cl18(ST)
CeCl3-LiCl-RbCl
GSalt-liquid LiCl(ST) RbCl(ST) LiRbCl2(ST) CeCl3(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCe2Cl7(ST)
CeCl3-NaCl-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CeCl3(ST) Na3Ce5Cl18(ST) Rb2CeCl5(ST) Rb3CeCl6(ST) RbCe2Cl7(ST)
CoCl2-FeCl2-FeCl3
BSalt-liquid MCl2_SOLID FeCl3(ST) CoFe2Cl8(ST)
CoCl2-FeCl2-KCl
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST)
CoCl2-FeCl2-LiCl
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) Li6FeCl8(ST) Li4CoCl6(ST)
CoCl2-FeCl2-MgCl2
BSalt-liquid MCl2_SOLID
CoCl2-FeCl2-MnCl2
BSalt-liquid MCl2_SOLID
CoCl2-FeCl2-NaCl
BSalt-liquid MCl2_SOLID AAlk2MX4(J-option) NaCl(ST)
CoCl2-FeCl2-NiCl2
BSalt-liquid MCl2_SOLID(I-option)
CoCl2-FeCl3-KCl
BSalt-liquid KCl(ST) FeCl3(ST) KFeCl4(ST) CoCl2(ST) KCoCl3(ST) K2CoCl4(ST) CoFe2Cl8(ST)
CoCl2-FeCl3-LiCl
BSalt-liquid BAlkCl-ss_rocksalt (J-option) FeCl3(ST) LiFeCl4(ST) CoCl2(ST) LiCoCl3(ST) Li2CoCl4(ST) Li4CoCl6(ST) CoFe2Cl8(ST)
CoCl2-FeCl3-MgCl2
BSalt-liquid MCl2_SOLID FeCl3(ST) MgFe2Cl8(ST) CoFe2Cl8(ST)
CoCl2-FeCl3-MnCl2
BSalt-liquid MCl2_SOLID FeCl3(ST) MnFe2Cl8(ST) CoFe2Cl8(ST)
CoCl2-FeCl3-NaCl
BSalt-liquid NaCl(ST) FeCl3(ST) NaFeCl4(ST) CoCl2(ST) Na2CoCl4(ST) CoFe2Cl8(ST)
CoCl2-FeCl3-NiCl2
BSalt-liquid MCl2_SOLID (I-option) FeCl3(ST) CoFe2Cl8(ST) NiFe2Cl8(ST)
CoCl2-KCl-LiCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) CoCl2(ST) Li4CoCl6(ST)
CoCl2-KCl-MgCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K3Mg2Cl7(ST)
CoCl2-KCl-MnCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
CoCl2-KCl-NaCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) CoCl2(ST)
CoCl2-KCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST)
CoCl2-LiCl-MgCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) Li4CoCl6(ST)
CoCl2-LiCl-MnCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) Li4CoCl6(ST)
CoCl2-LiCl-NaCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) CoCl2(ST) Li4CoCl6(ST)
CoCl2-LiCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) Li4CoCl6(ST) Li6NiCl8(ST)
CoCl2-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID
CoCl2-MgCl2-NaCl
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) NaCl(ST)
CoCl2-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option)
CoCl2-MnCl2-NaCl
BSalt-liquid MCl2_SOLID AAlk2MX4 (J-option) NaCl(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
CoCl2-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option)
CoCl2-NaCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4 (J-option) NaCl(ST)
CsCl-KCl-LaCl3
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
LaCl3(ST) K2LaCl5(ST) K3La5Cl18(ST) Cs3LaCl6(ST) CsLa2Cl7(ST)
CsCl-KCl-LiCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST) LiCs2Cl3(ST)
CsCl-KCl-MgCl2
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
AAlkCl-ss_rocksalt (J-option) MgCl2(ST) K3Mg2Cl7(ST) CsCl(ST) CsMg3Cl7(ST) Cs3MgCl5(ST)
CsCl-KCl-NaCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
CsCl-KCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
CsCl-KCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) SrCl2(ST) SrCl2(ST2) KSr2Cl5(ST) CsCl(ST)
CsCl-LaCl3-LiCl
GSalt-liquid LiCl(ST) CsCl(ST) CsCl(ST2)
LiCs2Cl3(ST) LaCl3(ST) Cs3LaCl6(ST) CsLa2Cl7(ST)
CsCl-LaCl3-NaCl
GSalt-liquid NaCl(ST) CsCl(ST) CsCl(ST2)
LaCl3(ST) Na3La5Cl18(ST) Cs3LaCl6(ST) CsLa2Cl7(ST)
CsCl-LaCl3-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
LaCl3(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbLa2Cl7(ST) Cs3LaCl6(ST) CsLa2Cl7(ST)
CsCl-LiCl-MgCl2
DSalt-liquid MCl2_SOLID BAMX3-Perovskite (J-option)
BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) CsCl(ST) LiCs2Cl3(ST) CsMg3Cl7(ST) Cs3MgCl5(ST)
CsCl-LiCl-NaCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
LiCs2Cl3(ST)
CsCl-LiCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) LiRbCl2(ST) CsCl(ST) LiCs2Cl3(ST)
CsCl-LiCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) LiCl(ST)
SrCl2(ST) SrCl2(ST2) CsCl(ST) CsCl(ST2)
LiCs2Cl3(ST)
CsCl-MgCl2-NaCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
NaCl(ST) MgCl2(ST) CsCl(ST) CsCl(ST2)
CsMg3Cl7(ST) Cs3MgCl5(ST)
CsCl-MgCl2-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
AAlkCl-ss_rocksalt (J-option) MgCl2(ST) CsCl(ST)
CsMg3Cl7(ST) Cs3MgCl5(ST)
CsCl-MgCl2-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss)
BAlk2MX4 (J-option) MgCl2(ST) SrCl2(ST2) CsCl(ST)
CsCl(ST2) CsMg3Cl7(ST) Cs3MgCl5(ST)
CsCl-NaCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) CsCl(ST)
CsCl-NaCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) NaCl(ST)
SrCl2(ST) SrCl2(ST2) CsCl(ST) CsCl(ST2)
CsCl-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) SrCl2(ST) SrCl2(ST2) RbSr2Cl5(ST) CsCl(ST)
FeCl2-FeCl3-KCl
BSalt-liquid KCl(ST) FeCl2(ST) FeCl3(ST) KFeCl3(ST) KFeCl4(ST) K2FeCl4(ST)
FeCl2-FeCl3-LiCl
BSalt-liquid BAlkCl-ss_rocksalt (J-option) FeCl2(ST) FeCl3(ST) LiFeCl4(ST) Li2FeCl4(ST) Li6FeCl8(ST)
FeCl2-FeCl3-MgCl2
BSalt-liquid MCl2_SOLID FeCl3(ST) MgFe2Cl8(ST)
FeCl2-FeCl3-MnCl2
BSalt-liquid MCl2_SOLID FeCl3(ST) MnFe2Cl8(ST)
FeCl2-FeCl3-NaCl
BSalt-liquid NaCl(ST) FeCl2(ST) FeCl3(ST) NaFeCl4(ST) Na2FeCl4(ST)
FeCl2-FeCl3-NiCl2
BSalt-liquid MCl2_SOLID (I-option) FeCl3(ST) NiFe2Cl8(ST)
FeCl2-KCl-LiCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) FeCl2(ST) Li6FeCl8(ST)
FeCl2-KCl-MgCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K3Mg2Cl7(ST)
FeCl2-KCl-MnCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
FeCl2-KCl-NaCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) FeCl2(ST)
FeCl2-KCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST)
FeCl2-LiCl-MgCl2
BSalt-liquid MCl2_SOLID AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) Li6FeCl8(ST)
FeCl2-LiCl-MnCl2
BSalt-liquid MCl2_SOLID AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) Li6FeCl8(ST)
FeCl2-LiCl-NaCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) FeCl2(ST) Li6FeCl8(ST)
FeCl2-LiCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) Li6FeCl8(ST) Li6NiCl8(ST)
FeCl2-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID
FeCl2-MgCl2-NaCl
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) NaCl(ST)
FeCl2-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option)
FeCl2-MnCl2-NaCl
BSalt-liquid MCl2_SOLID AAlk2MX4 (J-option) NaCl(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
FeCl2-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option)
FeCl2-NaCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4 (J-option) NaCl(ST)
FeCl3-KCl-LiCl
BSalt-liquid KCl(ST) LiCl(ST) FeCl3(ST) LiFeCl4(ST) KFeCl4(ST)
FeCl3-KCl-MgCl2
BSalt-liquid KCl(ST) MgCl2(ST) KMgCl3(ST)
K2MgCl4(ST) K3Mg2Cl7(ST) FeCl3(ST) MgFe2Cl8(ST) KFeCl4(ST)
FeCl3-KCl-MnCl2
BSalt-liquid KCl(ST) MnCl2(ST) KMnCl3(ST) K4MnCl6(ST) K3Mn2Cl7(ST) FeCl3(ST) KFeCl4(ST) MnFe2Cl8(ST)
FeCl3-KCl-NaCl
BSalt-liquid BAlkCl-ss_rocksalt (J-option) FeCl3(ST) NaFeCl4(ST) KFeCl4(ST)
FeCl3-KCl-NiCl2
BSalt-liquid KCl(ST) FeCl3(ST) KFeCl4(ST) NiCl2(ST) KNiCl3(ST) NiFe2Cl8(ST)
FeCl3-LiCl-MgCl2
BSalt-liquid MCl2_SOLID BAlkCl-ss_rocksalt (J-option)
FeCl3(ST) LiFeCl4(ST) MgFe2Cl8(ST)
FeCl3-LiCl-MnCl2
BSalt-liquid BAlkCl-ss_rocksalt (J-option) MnCl2(ST) Li2MnCl4(ST) FeCl3(ST) LiFeCl4(ST) MnFe2Cl8(ST)
FeCl3-LiCl-NaCl
BSalt-liquid BAlkCl-ss_rocksalt (J-option) FeCl3(ST) LiFeCl4(ST) NaFeCl4(ST)
FeCl3-LiCl-NiCl2
BSalt-liquid BAlkCl-ss_rocksalt (J-option) FeCl3(ST) LiFeCl4(ST) NiCl2(ST) Li2NiCl4(ST) Li6NiCl8(ST) NiFe2Cl8(ST)
FeCl3-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID FeCl3(ST) MgFe2Cl8(ST) MnFe2Cl8(ST)
FeCl3-MgCl2-NaCl
BSalt-liquid NaCl(ST) MgCl2(ST) NaMgCl3(ST) Na2MgCl4(ST) FeCl3(ST) NaFeCl4(ST) MgFe2Cl8(ST)
FeCl3-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) FeCl3(ST) MgFe2Cl8(ST) NiFe2Cl8(ST)
FeCl3-MnCl2-NaCl
BSalt-liquid NaCl(ST) MnCl2(ST) Na2MnCl4(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST) FeCl3(ST) NaFeCl4(ST) MnFe2Cl8(ST)
FeCl3-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) FeCl3(ST) MnFe2Cl8(ST) NiFe2Cl8(ST)
FeCl3-NaCl-NiCl2
BSalt-liquid NaCl(ST) FeCl3(ST) NaFeCl4(ST) NiCl2(ST) NiFe2Cl8(ST)
KCl-LaCl3-LiCl
GSalt-liquid KCl(ST) LiCl(ST) LaCl3(ST) K2LaCl5(ST) K3La5Cl18(ST)
KCl-LaCl3-NaCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) LaCl3(ST) Na3La5Cl18(ST) K2LaCl5(ST) K3La5Cl18(ST)
KCl-LaCl3-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) LaCl3(ST) K2LaCl5(ST) K3La5Cl18(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbLa2Cl7(ST)
KCl-LiCl-MgCl2
ASalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) K3Mg2Cl7(ST) LiKMgCl4(ST)
KCl-LiCl-MnCl2
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) MnCl2(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
KCl-LiCl-NaCl
ASalt-liquid AAlkCl-ss_rocksalt (J-option)
KCl-LiCl-NiCl2
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) NiCl2(ST) Li6NiCl8(ST)
KCl-LiCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) LiRbCl2(ST)
KCl-LiCl-SrCl2
DSalt-liquid BAlk2MX4 (J-option) KCl(ST) LiCl(ST)
SrCl2(ST) SrCl2(ST2) KSr2Cl5(ST)
KCl-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K3Mg2Cl7(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
KCl-MgCl2-NaCl
ASalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) MgCl2(ST) K3Mg2Cl7(ST)
KCl-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) KCl(ST) K3Mg2Cl7(ST)
KCl-MgCl2-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) MgCl2(ST) K3Mg2Cl7(ST)
KCl-MgCl2-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) BAlk2MX4 (J-option) KCl(ST) MgCl2(ST) K3Mg2Cl7(ST) SrCl2(ST2) KSr2Cl5(ST)
KCl-MnCl2-NaCl
BSalt-liquid AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option) MnCl2(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
KCl-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option)
KCl(ST) K4MnCl6(ST) K3Mn2Cl7(ST)
KCl-NaCl-NiCl2
BSalt-liquid AAMX3-Perovskite (J-option)
BAlkCl-ss_rocksalt (J-option) NiCl2(ST)
KCl-NaCl-PbCl2
HSalt-liquid AAlkCl-ss_rocksalt (J-option) PbCl2(ST) K2PbCl4(ST) KPb2Cl5(ST)
KCl-NaCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option)
KCl-NaCl-SrCl2
DSalt-liquid BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option)
SrCl2(ST) SrCl2(ST2) KSr2Cl5(ST)
KCl-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) AlkM2Cl5 (I-option) BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) SrCl2(ST) SrCl2(ST2)
LaCl3-LiCl-NaCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) LaCl3(ST) Na3La5Cl18(ST)
LaCl3-LiCl-RbCl
GSalt-liquid LiCl(ST) RbCl(ST) LiRbCl2(ST) LaCl3(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbLa2Cl7(ST)
LaCl3-NaCl-RbCl
GSalt-liquid AAlkCl-ss_rocksalt (J-option) LaCl3(ST) Na3La5Cl18(ST) Rb2LaCl5(ST) Rb3LaCl6(ST) RbLa2Cl7(ST)
LiCl-MgCl2-MnCl2
BSalt-liquid MCl2_SOLID AAlk2MX4(J-option)
BAlkCl-ss_rocksalt (J-option)
LiCl-MgCl2-NaCl
ASalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option)
LiCl-MgCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4(J-option)
BAlkCl-ss_rocksalt (J-option) Li6NiCl8(ST)
LiCl-MgCl2-RbCl
DSalt-liquid MCl2_SOLID BAMX3-Perovskite (J-option)
BAlk2MX4 (J-option) AAlkCl-ss_rocksalt (J-option) LiRbCl2(ST)
LiCl-MgCl2-SrCl2
DSalt-liquid MCl2_SOLID (Ca,Sr,[Ba,Mg])Cl2(ss)
AAlkCl-ss_rocksalt (J-option) SrCl2(ST2)
LiCl-MnCl2-NaCl
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
MnCl2(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
LiCl-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4 (J-option)
BAlkCl-ss_rocksalt (J-option) Li6NiCl8(ST)
LiCl-NaCl-NiCl2
BSalt-liquid AAlk2MX4 (J-option) BAlkCl-ss_rocksalt (J-option)
NiCl2(ST) Li6NiCl8(ST)
LiCl-NaCl-RbCl
DSalt-liquid AAlkCl-ss_rocksalt (J-option) LiRbCl2(ST)
LiCl-NaCl-SrCl2
DSalt-liquid AAlkCl-ss_rocksalt (J-option) SrCl2(ST) SrCl2(ST2)
LiCl-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) LiCl(ST)
RbCl(ST) LiRbCl2(ST) SrCl2(ST) SrCl2(ST2) RbSr2Cl5(ST)
MgCl2-MnCl2-NaCl
BSalt-liquid MCl2_SOLID AAMX3-Perovskite (J-option)
AAlk2MX4 (J-option) NaCl(ST) Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
MgCl2-MnCl2-NiCl2
BSalt-liquid MCl2_SOLID (I-option)
MgCl2-NaCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAMX3-Perovskite (J-option) AAlk2MX4 (J-option) NaCl(ST)
MgCl2-NaCl-RbCl
DSalt-liquid BAMX3-Perovskite (J-option) BAlk2MX4 (J-option)
AAlkCl-ss_rocksalt (J-option) MgCl2(ST)
MgCl2-NaCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) BAlk2MX4 (J-option) NaCl(ST) MgCl2(ST) SrCl2(ST2)
MgCl2-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) BAlk2MX4 (J-option) RbCl(ST) MgCl2(ST) SrCl2(ST2)
RbSr2Cl5(ST)
MnCl2-NaCl-NiCl2
BSalt-liquid MCl2_SOLID (I-option) AAlk2MX4 (J-option) NaCl(ST)
Na6MnCl8(ST) Na2Mn3Cl8(ST) NaMn4Cl9(ST) Na9Mn11Cl31(ST)
NaCl-RbCl-SrCl2
DSalt-liquid BAMX3-Perovskite (J-option)
AAlkCl-ss_rocksalt (J-option) SrCl2(ST) SrCl2(ST2) RbSr2Cl5(ST)
Anion = F
CaF2-KF-LiF
ASalt-liquid CAMX3-Perovskite (J-option) LiF(ST)
KF(ST) CaF2(ST) CaF2(ST2)
CaF2-KF-MgF2
ASalt-liquid CAMX3-Perovskite (J-option) CAlk2MX4 (J-option) MgF2(ST) KF(ST) CaF2(ST) CaF2(ST2)
CaF2-KF-NaF
ASalt-liquid CAMX3-Perovskite (J-option) AlkF(ssA) (J-option) CaF2(ST) CaF2(ST2)
CaF2-LiF-MgF2
ASalt-liquid MgF2-[LiF](ss) LiF-[MgF2](ss) CaF2(ST)
CaF2(ST2)
CaF2-LiF-NaF
ASalt-liquid NaF-[LiF](ss) LiF(ST) CaF2(ST) CaF2(ST2)
CaF2-MgF2-NaF
ASalt-liquid CAMX3-Perovskite (J-option) NaF(ST) MgF2(ST) CaF2(ST) CaF2(ST2)
CsF-KF-LiF
ESalt-liquid AlkF(ssA) (J-option) AlkF(ssB) (J-option) LiF(ST) LiCsF2(ST)
CsF-KF-NaF
ESalt-liquid AlkF(ssA) (J-option) AlkF(ssB) (J-option)
CsF-KF-RbF
ESalt-liquid AlkF(ssA) (J-option) AlkF(ssB) (J-option)
CsF-LiF-NaF
ESalt-liquid NaF-[LiF](ss) AlkF(ssA) (J-option) LiF(ST) LiCsF2(ST)
CsF-LiF-RbF
ESalt-liquid AlkF(ssA) (J-option) LiF(ST) LiRbF2(ST) LiCsF2(ST)
CsF-NaF-RbF
ESalt-liquid AlkF(ssA) (J-option)
KF-LiF-MgF2
ASalt-liquid CAMX3-Perovskite (J-option) MgF2-[LiF](ss) LiF-[MgF2](ss) CAlk2MX4 (J-option) KF(ST)
KF-LiF-NaF
ASalt-liquid NaF-[LiF](ss) AlkF(ssA) (J-option) LiF(ST)
KF-LiF-RbF
ESalt-liquid AlkF(ssA) (J-option) LiF(ST) LiRbF2(ST)
KF-MgF2-NaF
ASalt-liquid CAMX3-Perovskite (J-option) CAlk2MX4 (J-option)
AlkF(ssA) (J-option) MgF2(ST)
KF-NaF-RbF
ESalt-liquid AlkF(ssA) (J-option)
LiF-MgF2-NaF
ASalt-liquid CAMX3-Perovskite (J-option) NaF-[LiF](ss) MgF2-[LiF](ss) LiF-[MgF2](ss)
LiF-NaF-RbF
ESalt-liquid NaF-[LiF](ss) AlkF(ssA) (J-option) LiF(ST) LiRbF2(ST)
TABLE 4 : List of phases for some RECIPROCAL TERNARY systems :
Only the MAIN reciprocal ternary systems are presented below. These are systems for which the two anions are Cl and F and the cations are two of Li, Na, K, Mg and Ca.
Reciprocal ternary phase diagrams (those containing two cations and two anions) may be calculated using the phases listed below for each system. The following code of colours is used:
- For all reciprocal ternary systems in purple, complete assessments based on all experimental data from the literature are available. Reciprocal ternary parameters were added for the liquid and/or other phases (solid solutions) if needed.
- For all reciprocal ternary systems in blue, no experimental data could be found in the literature. Consequently, the thermodynamic properties of the liquid (and solid solutions if they exist) are simply estimated from the optimized parameters of the 4 binary common ion subsystems using proper interpolation methods.
Beware - if some ternary or quaternary phases are unknown, incorrect phase equilibria may be calculated.
Phases accompanied by “(ST)” indicate stoichiometric phases. These phases must be selected from the FTsalt compound database. When 2 or more allotropes exist for a solid, the notations (ST), (ST2), (ST3),… are used.
(J-option) ― the phase may display a 3-phase immiscibility; selection with the J-option is required.
Ca, K // Cl, F
ASalt-liquid (J-option) CAMX3-Perovskite (J-option) KCl(ST)
KF(ST) CaF2(ST) CaF2(ST2) CaCl2(ST) CaFCl(ST)
Ca, Li // Cl, F
ASalt-liquid (J-option) LiCl(ST) LiF(ST) CaF2(ST) CaF2(ST2) CaCl2(ST) CaFCl(ST)
Ca, Mg // Cl, F
ASalt-liquid (J-option) (Ca,Sr,[Ba,Mg])Cl2(ss) MgF2(ST) MgCl2(ST) CaF2(ST) CaF2(ST2) CaFCl(ST)
Ca, Na // Cl, F
ASalt-liquid (J-option) AAlkCl-ss_rocksalt (J-option) NaF(ST) CaF2(ST) CaF2(ST2) CaCl2(ST) CaFCl(ST)
K, Li // Cl, F
ASalt-liquid (J-option) KCl(ST) LiCl(ST) KF(ST) LiF(ST)
K, Mg // Cl, F
ASalt-liquid (J-option) CAMX3-Perovskite (J-option) CAlk2MX4 (J-option)
KCl(ST) MgF2(ST) MgCl2(ST) KF(ST) K3Mg2Cl7(ST)
K, Na // Cl, F
ASalt-liquid (J-option) AlkF(ssA) (J-option) AAlkCl-ss_rocksalt (J-option)
Li, Mg // Cl, F
ASalt-liquid (J-option) MCl2_SOLID MgF2-[LiF](ss) LiF-[MgF2](ss)
AAlkCl-ss_rocksalt (J-option)
Li, Na // Cl, F
ASalt-liquid (J-option) NaF-[LiF](ss) AAlkCl-ss_rocksalt (J-option)
LiF(ST)
Mg, Na // Cl, F
ASalt-liquid (J-option) CAMX3-Perovskite (J-option) CAlk2MX4 (J-option) NaCl(ST) NaF(ST) MgF2(ST) MgCl2(ST)
