LIST OF SOLUTIONS AND COMPOUNDS IN FToxid

(1) LIST OF SOLUTIONS

FToxid-SLAG

Slag-liq oxide (Mis.gap at high SiO2,use I option) Al,As,B,Ca,Co,Cr,Cu,Fe,Ge,

K,Mg,Mn,Na,Ni,Pb,Si,Sn,Ti,Zn,Zr; dilute S,SO4,PO4,H2O/OH,CO3,F,Cl,I

FToxid-SPIN

Spinel Al-Co-Cr-Fe-Mg-Ni-Zn-O (Replaces SpMg,FeSP,FZSP). Possible miscibility

gap between Fe(3+)-rich and Al-rich. (Do not select both SPIN and AlSp)

FToxid-MeO_

Monoxide Rocksalt-str replaces WUST. Fe(2),Ca,Mg,Ni,Co,Mn;dilute Zn,Al,Cr,Fe(3)

Mis. gap if CaO is present (use I option). Do not select both MONO and MeO_.

FToxid-cPyr

Clinopyroxene (Ca,Mg,Fe)[Mg,Fe,Fe3+,Al]{Al,Fe3+,Si}SiO6 Possible miscibility gap

when Ca is present (use I option). (Do not use simultaneously with MnPy)

FToxid-oPyr

Orthopyroxene (Ca,Mg,Fe)[Mg,Fe,Fe3+,Al]{Al,Fe3+,Si}SiO6 Possible miscibility gap

when Ca is present (use I option). (Do not use simultaneously with MnPy)

FToxid-pPyr      

Protopyroxene (Ca,Mg,Fe)[Mg,Fe,Fe3+,Al]{Al,Fe3+,Si}SiO6 Possible miscibility gap

when Ca is present (use I option). (Do not use simultaneously with MgPy or MnPy)

FToxid-LcPy   

LowClinopyroxene {Ca,Mg}1{Mg}1(Si)2(O)6

Possible miscibility gap (use I option). Do not select simultaneously with MnPy

FToxid-WOLL   

Wollastonite, CaSiO3; dilute MgSiO3, FeSiO3, MnSiO3

FToxid-bC2S   

a'Ca2SiO4  (alpha-prime Ca2SiO4); dilute Mg,Fe,Mn,Pb,Zn (bC2SA) or B (bC2SB).

Replaces FACT-CASI.

FToxid-aC2S

a-Ca2SiO4 (alpha-Ca2SiO4); dilute Fe,Mg,Mn (aC2SA) or B (aC2SB).

FToxid-Mel_

Melilite (Ca,Pb)2[Zn,Mg,Fe2+,Fe3+,Al]{Fe3+,Al,Si}2O7

Replaces FACT-MELZ, FACT-MELA

FToxid-Oliv

Olivine [Ca,Mg,Fe,Mn,Co,Zn,Ni]1[Ca,Mg,Fe,Mn,Co,Zn,Ni]1[Si]1[O]4.   Possible mis.

gap when Ca is present (use I option). Replaces MONT, FORS, CFSM, Oli1 and Oli2.

FToxid-Cord

Cordierite Al4(Mg,Fe)2Si5O18

FToxid-MulF

Mullite solution Al6Si2O13; dilute Fe6Si2O13

(Select only one of MULL, MulB or MulF)

FToxid-CAFS

Ca2(Al,Fe)8SiO16     X-phase: (CaO)2[(Al,Fe)2O3]4SiO2

FToxid-CAF6

Ca(Al,Fe)12O19      CaAl12O19; dilute CaFe12O19

FToxid-CAF3

Ca(Al,Fe)6O10   T-phase (pure end-members are not stable)

FToxid-CAF2

Ca(Al,Fe)4O7     CaAl4O7; dilute CaFe4O7

FToxid-CAF1

Ca(Al,Fe)2O4    Possible miscibility gap (use I option).

FToxid-C2AF

Ca2(Al,Fe)2O5    Ca2Fe2O5; dilute Ca2Al2O5

FToxid-C3AF

Ca3(Al,Fe)2O6    Ca3Al2O6; dilute Ca3Fe2O6

FToxid-CORU

M2O3(Corundum) Al2O3-Cr2O3-Fe2O3 solid solution

Possible miscibility gap (use I option).

FToxid-GARN

Garnets Ca3(Cr,Al)2Si3O12

FToxid-CaSp

CaSpinel Ca(Cr,Fe)2O4

FToxid-ZNIT

Zincite ZnO; dilute CoO, FeO, Fe2O3, MgO, MnO, NiO.

Phase must be rich in ZnO, otherwise invalid.

FToxid-WILL

Willemite  (Zn,Fe2+,Mg)[Zn,Fe2+,Mg]SiO4,  Zn2SiO4-rich only.

Replaces solutions WILL and WILF.

FToxid-MgPy

Mg-Zn_Pyroxene: (Mg,Zn)1(Mg,Zn)1Si2O6 Protoenstatite Mg2Si2O6 dilute in Zn2Si2O6

(Do not select simultaneously with pPyr or MnPy)

FToxid-PbO_

PbO-ZnO solid solution (formerly PbO_). PbO; dilute ZnO.

FToxid-PCSi

Pb3M2Si3O11 solid solution: Pb3(Pb,Ca)2Si3O11

FToxid-NCSO

(Na2,Ca)Na2CaSi3O9 solid solution

FToxid-MulB

Mullite solution Al6Si2O13; dilute (Al2O3)9(B2O3)2

(Select only one of MULL, MulB or MulF)

FToxid-Qrtz

Quartz solid solution SiO2-GeO2.                                                                                                 

FToxid-TiO2

Rutile TiO2; dilute Ti2O3, ZrO2.

Valid only when TiO2-rich

FToxid-ILME

Ilmenite solid solution: FeTiO3-Ti2O3-MgTiO3-MnTiO3                                                                                                                       

FToxid-PSEU

Pseudobrookite solid solution: FeTi2O5-Ti3O5-MgTi2O5-MnTi2O5

FToxid-TiSp

Titania_Spinel (Fe,Mg,Mn)2TiO4 - MgTi2O4; dilute (Fe,Mn)Ti2O4.

Valid above 1050 K and only when Ti is a major constituent.

FToxid-CaTi

Ca3Ti2O7-Ca3Ti2O6 solid solution

FToxid-PERO

Perovskite Ca2Ti2O6-Ca2Ti2O5 solid solution

FToxid-MONO

Monoxide rocksalt structure:CaO,FeO,MgO,MnO,NiO; dilute Al2O3,Cu2O,TiO2,ZnO,ZrO2

Possible mis.gap if CaO present (use I option). Do not select both MONO and MeO_

FToxid-ZrOc

ZrO2-cubic solution, valid only when ZrO2-rich.

ZrO2; dilute Al2O3, CaO, FeO, MgO, MnO, TiO2

FToxid-ZrOt

ZrO2-tetragonal solution, valid only when ZrO2-rich

ZrO2; dilute Al2O3, CaO, FeO, MgO, MnO, TiO2

FToxid-Rhod

Rhodonite    MnSiO3; dilute CaSiO3, CoSiO3

FToxid-AlSp

Al-spinel (Fe,Mg,Mn)Al2O4-Al2O3

(Do not select both SPIN and AlSp)

FToxid-MnPy

Mn_Pyroxene (Mg,Fe,Mn)SiO3

(Do not select simultaneously with any of oPyr, cPyr, pPyr, LcPy, or MgPy.)

FToxid-ReAl

Re2O3+Al2O3_liquid (Re = rare earths) where Re = La, Ce, Pr, Nd, Pm, Sm,

Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu and Al (Do not use simultaneously with SLAG)

FToxid-MULL

Mullite non-stoichiometric compound.  Unless you require high accuracy,

convergence is faster and surer with stoichiometric mullite Al6Si2O13.

(2) LIST OF COMPOUNDS   (246 compounds)

Al11O18Ce	s	Al11O18Nd	s	Al11O18Pm	s
Al11O18Pr	s	Al2Ce4O9	s	Al2Er4O9	s
Al2Eu4O9	s	Al2Fe2O6	s	Al2Gd4O9	s
Al2Ho4O9	s	Al2La4O9	s	Al2Lu4O9	s
Al2Nd4O9	s	Al2O3	s1-s4,l	(Al2O3)2(B2O3)	s
(Al2O3)9(B2O3)2	s	Al2Pm4O9	s	Al2Pr4O9	s
Al2Si2O7	s			Al2Sm4O9	s
Al2TiO5	s	Al4TiO8	s	Al5Ce3O12	s
Al5Er3O12	s	Al5Eu3O12	s	Al5Gd3O12	s
Al5La3O12	s	Al5Lu3O12	s	Al5Nd3O12	s
Al5Pm3O12	s	Al5Pr3O12	s	Al5Sm3O12	s
Al5Yb3O12	s	Al6Si2O13	s	Al7La33O60	s
AlCeO3	s	AlDyO3	s	AlErO3	s
AlEuO3	s	AlGdO3	s	AlLaO3	s
AlLuO3	s	AlNdO3	s	AlPmO3	s
AlPrO3	s	AlSmO3	s	AlTbO3	s
AlTmO3	s	AlYbO3	s	B2O3	s,l
Ca2Al2SiO7	s	Ca2B2O5	s1,s2	(Ca2Cr3)Cr10O20	s
Ca2Fe2O5	s	Ca2FeSi2O7	s	Ca2Mg2Al28O46	s
Ca2MgSi2O7	s	Ca2SiO4	s1-s3	Ca2Ti2O5	s1,s2
Ca2ZnSi2O7	s	Ca3Al2O6	s	Ca3Al2Si3O12	s
Ca3B2O6	s	Ca3Cr2Si3O12	s	Ca3Fe2Si3O12	s
Ca3MgAl4O10	s	Ca3MgSi2O8	s	Ca3Si2O7	s
Ca3SiO5	s	Ca3Ti2O6	s	Ca3Ti2O7	s
Ca5Ti4O13	s	CaAl12O19	s	CaAl2O4	s
CaAl2Si2O8	s1,s2	CaAl2SiO6	s	CaAl4O7	s
CaB2O4	s	CaB2Si2O8	s	CaB4O7	s
(CaCr)Si4O10	s	CaCr2O4	s1,s2	CaFe2O4	s
CaFe4O7	s	CaFeSi2O6	s	CaMg2Al16O27	s
CaMgSi2O6	s	CaO	s,l	(CaO)2(PbO2)	s
CaSiO3	s1,s2	CaSiTiO5	s	CaTiO3	s1,s2
CaZrO3	s	Ce2O3	s,l	Co2SiO4	s
CoO	s,l	Cr2O3	s,l	Cr3O4	s
CrO	l	Cu2Al2O4	s	Cu2O	s,l
CuO	s	Dy2O3	s,l	Dy3Al5O12	s
Dy4Al2O9	s	Er2O3	s1,s2,l	Eu2O3	s1,s2,l
Fe2Al4Si5O18	s	Fe2O3	s1-s3	Fe2SiO4	s1-s3
Fe3Al2Si3O12	s	(FeO)(TiO2)	s	(FeO)2(TiO2)	s
FeSiO3	s1-s3	FeTi2O4	s	FeTi2O5	s
Gd2O3	s,l	GeO2	s1,s2,l	Ho2O3	s1,s2,l
Ho3Al5O12	s	HoAlO3	s	K2Al12O19	s
K2O	s,l	K2Si2O5	s1-s3	K2Si4O9	s1,s2
K2SiO3	s	K2Ti2O5	s	K2Ti3O7	s
K2Ti6O13	s	K2TiO3	s	K4TiO4	s
K8Ti5O14	s	KAl9O14	s	KAlO2	s1,s2
KAlSi2O6	s1,s2	KAlSi3O8	s1-s3	KAlSiO4	s1,s2
La2O3	s,l	LaAl11O18	s	Lu2O3	s,l
Mg2Al4Si5O18	s	Mg2B2O5	s	Mg2SiO4	s1-s3
Mg2TiO4	s1,s2	Mg3Al2Si3O12	s	Mg3B2O6	s
Mg4Al10Si2O23	s	MgB4O7	s	MgO	s,l
MgSiO3	s1-s7	MgTi2O5	s	MgTiO3	s
Mn2Al4Si5O18	s	Mn2SiO4	s	Mn2TiO4	s1,s2
Mn3Al2Si3O12	s	MnAl2O4	s	MnO	s,l
(MnO)(TiO2)	s	MnSiO3	s	MnTi2O4	s1,s2
MnTi2O5	s	Na2Al12O19	s	Na2B4O7	s
Na2B8O13	s	Na2Ca2Si3O9	s	Na2Ca3Si6O16	s
Na2CaSi5O12	s	Na2Fe2O4	s	Na2Mg2Si6O15	s
Na2MgSi4O10	s	Na2O	s1-s3,l	(Na2O)(TiO2)3	s
(Na2O)(TiO2)6	s	Na2Si2O5	s1-s3	Na2SiO3	s
Na2TiO3	s1,s2	Na4B2O5	s	Na4CaSi3O9	s
Na4SiO4	s	Na4TiO4	s	Na6Si2O7	s
Na6Si8O19	s	Na8Ti5O14	s	NaAl9O14	s
NaAlO2	s1,s2	NaAlSi2O6	s	NaAlSi3O8	s1,s2
NaAlSiO4	s1-s4	NaB3O5	s	NaB5O8	s
NaB9O14	s	NaBO2	s	Nd2O3	s1,s2,l
Ni2SiO4	s	NiCaSi2O6	s	NiO	s,l
Pb10Fe2Si2O17	s	Pb2Fe2O5	s	Pb2Fe2Si2O9	s
Pb2SiO4	s1,s2	Pb2ZnSi2O7	s	Pb3Ca2Si3O11	s
Pb4SiO6	s	Pb8CaSi6O21	s	Pb8ZnSi6O21	s
PbCa2Si3O9	s	PbFe10O16	s	PbFe4O7	s
PbO	s1,s2,l	(PbO)(Al2O3)	s	(PbO)(Al2O3)6	s
(PbO)2(Al2O3)	s	PbSiO3	s1,s2	PbZnSiO4	s
Pm2O3	s,l	Pr2O3	s,l	SiO2	s1-s8,l
Sm2O3	s1,s2,l	SnO	s	SnO2	s
Tb2O3	s,l	Tb3Al5O12	s	Tb4Al2O9	s
Ti10O19	s	Ti20O39	s	Ti2O3	s1,s2,l
Ti2ZrO6	s	Ti3O5	s1,s2	Ti4O7	s
Ti5O9	s	Ti6O11	s	Ti7O13	s
Ti8O15	s	Ti9O17	s	TiO2	s1,s2,l
Tm2O3	s1-s3,l	Tm3Al5O12	s	Tm4Al2O9	s
Yb2O3	s1-s3,l	Yb4Al2O9	s	Zn2SiO4	s
ZnO	s,l	ZrO2	s1-s3,l	ZrSiO4	s
ZrTiO4	s